北 京 化 工 大 学
《无机及分析化学实验（I）（A类）》教学大纲
一、课程基本信息
课程代码 （已开设课程填写） | CHM11204L | ||||||||
课程信息 （仅新开课程填写） | 所属 学科 | 化学 | 知识 领域 | 实验科学 | |||||
课程层次 | □本科生基础课程(通识教育及公共基础) □本科生中级课程(一级学科基础) □本科生高级课程(二级学科基础) □本科生深度课程(学科方向及特色) | ||||||||
总学时 | 64 | 学分 | 2.0 | 理论学时 | 2 | 实验学时 | 62 | 上机学时 | |
课程中文名称 | 无机及分析化学实验（I） | ||||||||
课程英文名称 | Experiments of Inorganic and Analytical Chemistry（I） | ||||||||
适用专业 | 应用化学专业，理科实验班 | ||||||||
开课学期 | |||||||||
预修课程（名称） | |||||||||
并修课程（名称） | 《无机化学》《分析化学》 | ||||||||
课程简介 | 大学化学实验不仅是传授知识、验证理论和掌握实验技能，更重要的是培养学生严谨的科学态度、严肃认真的工作作风和良好的化学素质，重在提高学生的能力，使学生能够运用所学知识解决实际问题，培养学生动手、观察、思考和表达的能力，提高学生的创新能力。 | ||||||||
建议教材 | 张丽丹等《新编大学化学实验》第一版，北京：化学工业出版社，2020年9月 | ||||||||
参 考 书 | 《无机化学》 《分析化学》《大学化学实验》 | ||||||||
二、课程教育目标
化学是一门实验科学，是高等学校工科（化工类）学生必不可少的必修课。科学技术的综合化、整体化趋势，要求学生系统掌握完整的化学实验知识，提高分析、综合、创新的能力。《无机及分析化学实验》以化学实验的基本操作技能训练、基础化学实验、综合化学实验和设计实验构筑实验课程体系，以适应新世纪发展对人才培养的要求。
《无机及分析化学实验》的课程教育目标是: 使学生掌握无机及分析化学实验的基本操作、基本技能以及各种实验仪器的使用方法；掌握无机化合物分离、提纯和制备的基本方法，引导学生仔细观察实验现象；理解实验的设计原理、理解定量分析方法的基本原理，树立“量”的概念，学会对实验数据进行正确处理和评价；了解一些常用的无机化合物的性质，并能进行定量分析的基本操作。此外，更重要的是培养学生严谨的科学态度、严肃认真的工作作风和良好的化学素质，重在提高学生的能力，使学生能够运用所学知识解决实际问题，培养学生动手、观察、思考和表达的能力，提高学生的创新能力。化学实验教学中心遵循“加强基本训练、着重能力培养、培养创新精神”的原则，融传授知识、培养能力和提高素质为一体，在实验教学中要求学生掌握化学研究的一般方法，重视基本操作技术，提高学生分析问题和解决问题的能力，尤其要鼓励创新，重视创新能力、实践能力、学习能力的培养。
三、理论教学与实践教学内容与要求
《无机及分析化学实验(I) 》 64学时 2.0学分
实验技术讲座 (2 学时)
《无机及分析化学实验》课程体系及内容简介；实验预习、记录和报告的要求和书写格式；实验结果的处理；化学实验基本常识；化学研究的基本方法。
实验一 固体和液体物质的称量 (3学时)
了解单盘天平的构造和称量原理；熟记分析天平的使用规则；掌握直接称量法和减量称量法；掌握在称量中有效数字的运用。
实验二 滴定分析基本操作及酸碱浓度的比较 (5学时)
学习滴定管的准备、使用、滴定操作及读数方法；学会正确判断酚酞、甲基橙两种指示剂的滴定终点。
实验三 氢氧化钠标准溶液的标定和工业醋酸含量的测定 (5 学时)
掌握NaOH标准溶液的配制方法；了解标定标准溶液的基准物应具备的条件；掌握NaOH滴定HAc的基本原理、指示剂的选择及结果计算；学会正确使用容量瓶、移液管。
实验四 pH 法测定醋酸的电离平衡常数和电离度 (4学时)
掌握电离平衡常数和电离度的测定原理和方法；学会酸度计的使用方法。
实验五(1) 碳酸钠的合成(4学时)
掌握联合制碱法的原理，了解通过复分解反应制备碳酸钠的方法；掌握恒温条件控制及高温灼烧基本操作。
实验五(2) 碳酸钠产品中总碱度的测定 (5 学时)
掌握HCl溶液的配制和标定方法；掌握双指示剂法测定混合碱的方法及结果计算。
实验六 (1)过碳酸钠合成 (4学时)
了解过氧键的性质，认识H2O2溶液固化的原理，学习低温下合成过碳酸钠的方法。
实验六 (2)过碳酸钠产品中含氧量测定（KMnO4法）(4学时)
掌握KMnO4溶液的配制及其以Na2C2O4为基准物的标定方法；掌握KMnO4法测定活性氧含量的原理和方法；通过用KMnO4标准溶液对过碳酸钠的氧化还原定量滴定，确定制备产品的活性氧含量。
实验七 元素及化合物性质(一) (5学时)
掌握p区主要非金属元素及化合物的性质；掌握p区主要非金属元素及化合物的分离与鉴定；学会元素性质试验及定性分析的基本操作。
实验八 元素及化合物性质(二) (4学时)
掌握d区、ds区氢氧化物或氧化物的生成和性质；掌握d区、ds区主要元素的性质及一些离子的鉴定；巩固元素性质试验及定性分析的基本操作。
实验九 配位化合物的形成和性质 (4 学时)
了解配位解离平衡及其他平衡之间的关系；从配离子解离平衡移动，比较其稳定性；掌握有关配合物的特征及其鉴定方法。
实验十 混合离子的分离与定性分析 (4 学时)
熟悉有关离子及其化合物的特性；了解离子分离条件的选择和检出条件的确定；加深对各类离子平衡知识的理解和实际应用。
实验十一： 洁厕灵中酸的定性和定量分析 (4学时)
熟悉洁厕灵中的主要化学组成；掌握洁厕灵中主要成分的定量分析方法；熟练掌握滴定分析的操作方法。
实验十二 草酸合铜（II）酸钾的制备和铜含量的测定 (7学时)
熟悉配合物草酸合铜(II)酸钾的合成方法；进一步掌握滴定法测定草酸合铜(II)酸钾中Cu的含量。
四、作业
每个实验结束后，学生要完成实验报告，在下次实验时交给老师。
五、考核方式及成绩评定
平时成绩占70％，其中预习报告为20％，实验操作占40％，实验报告40％；
期末实验操作考核或笔试成绩占30％。
张丽丹 靳兰 曹鼎 张春婷
2016年10月26日
化学实验教学中心
Beijing University of Chemical Technology
Syllabus for Experiments of Inorganic and Analytical Chemistry（I）
Ⅰ. General Information
Course Code ( if applied ) | CHM11204L | ||||||||
Course Information ( for new course only ) | Academic Discipline | Chemical | Knowledge Domain | Experiment | |||||
Total Class Hours | 64 | Credits | 2.0 | Lecture Hours | 2 | Laboratory Hours | 62 | Computer Lab Hours | |
Course Title (in Chinese) | 无机及分析化学实验 (I) | ||||||||
Course Title (in English) | Experiments of Inorganic and Analytical Chemistry（I） | ||||||||
Applicable Majors | Applied chemistry, science development class | ||||||||
Semester Available | □ Spring □ Autumn □ Summer | ||||||||
Prerequisites (Course Title) | |||||||||
Corequisites (Course Title) | 《Inorganic Chemistry》 《Analytical Chemistry》 | ||||||||
Brief Course Description | Experiment of Chemistry is not only to impart knowledge, but also to verify the theory and master the skills of experiment. It is more important to help students develop the rigorous scientific attitude, serious style of work and good chemical quality with emphasis on improving students' abilities, especially the abilities of innovation. | ||||||||
Textbooks Recommended | Yikan Ke,etc，college chemical experiments (Second edition)，chemical industrial press, Beijing，2010. | ||||||||
References | 《Inorganic Chemistry》 《Analytical Chemistry》 《Experiments of Chemistry》 | ||||||||
Ⅱ. Teaching Objectives
Experiment of Chemistry is an experimental science. Therefore, the chemistry experiment courses are compulsory courses of colleges of engineering (esp. Chemical engineering). With the integration and systematic trend of science and technology, it is necessary that students grasp the systematic knowledge of chemistry experiments, analysis, synthesis, and the ability to innovate. Experiments of Inorganic and Analytical Chemistry in the courses of University base on basic skills training of the chemical experiments, comprehensive chemical experiments and designing experiments to build experimental curriculum system, and to adapt to the requirements of the new century.
The goals of Experiments of Inorganic and Analytical Chemistry are as following: let students grasp the basic operations, basic skills and know how to use the instruments of Inorganic and Analytical Chemical experiments; Mastering the basic methods for separation, purification and preparation of inorganic compounds, then guide the students to observe the experimental phenomena carefully; Understanding the design principles, quantitative analysis methods of experiments, and the concept of “quantity”. Let students learn how to analysis and evaluate the experimental data. Let students understand the properties of common inorganic compounds, and master the basic operation of quantitative analysis. In addition，It is more important for Experiments of Inorganic and Analytical Chemistry to help students develop the rigorous scientific attitude, serious style of work and good chemical quality with emphasis on improving students' abilities, especially the abilities of innovation. Chemical experimental teaching center follow the strengthening of basic training, focusing on capacity-building, and cultivating the spirit of innovation; impart knowledge, build capacity and improve the quality as a whole. Chemical experimental teaching center put emphasis on basic operating techniques of experiment, the abilities to analyze problems and solve problems, in particular, to encourage innovation, practical ability and learning ability.
Ⅲ. Teaching Content and Requirements for the Lecturing Part and Practical Part
Experiments of Inorganic and Analytical Chemistry（I）
(Total Course Hours:64hours，Credits:2.0)
Lecture on experimental technology (2.0 hours)
In this section, students will be told to learn the content of the course, how to preview the course, record the data and write report of the experiment. Dealing the experimental results, basic acknowledges of the experiment and the basic research methods are also introduced to the students.
Experiment one: weight or measurement to the solid and liquid reagents (3 hours).
In this experiment, students are required to master the structure of single arm balance and master the use of analytical balance; they are also required to master the method of weigh directly and decrement weighing method to a solid material, to master how to deal with effect data.
Experiment two: basic operation of titration and comparison on densities of acid and alkali (5 hours)
Students are asked to master the use of buret and to judge the end point of titration using phenothalin and methyl orange as indicators .
Experiment three: calibration on standard solution of NaOH and content measurement of industrial HAC (5 hours).
Students are required to master the method on preparing standard solution of NaOH, to learn the conditions on standard substance in experiment, to master the basic theory using NaOH titrating to HAC, to master how to select indicator, how to use the volumetric flask and transfer pipet.
Experiment four: measurement on Ionization equilibrium constant of HAC by pH method (4 hours)
In this experiment, students are required to master the theory and method on how to measure the Ionization equilibrium constant and use of pH meter.
Experiment five (1): synthesis of Na2CO3 (4 hours)
In this experiment, the students are required to master the method on Hou's process, control on stable temperature and calcination on high temperature.
Experiment five (2): measurement on total basis in Na2CO3 prepared (5 hours)
In this experiment, students are required to master the method on how to preparation of HCl solution and calibration, the method on measurement of mixed alkali by double indicators and how to deal with the result.
Experiment six (1): synthesis of Na2CO3·mH2O2 (4 hours)
Students are required to understand the properties of [O-O], control on stable temperature and calcination on low temperature.
Experiment six (2): measurement the [O-O] value in Na2CO3·mH2O2 (4 hours)
In this experiment, students are required to master the method on how to preparation of KMnO4solution and calibration, the method on measurement the [O-O] value in Na2CO3·mH2O2 and how to deal with the result.
Experiment seven: properties of elements and compounds (I) (4 hours)
In this experiment, the students are required to master the properties of elements in P area and their compounds. They are also required to master how to analysis these elements.
Experiment eight: properties of elements and their compounds (II) (4 hours)
Students are required to master synthesis the hydroxide and oxidizing material of elements in d area and ds area, to master the properties of these elements and how to analysis these elements and their compounds.
Experiment nine: formations on coordination compound and their properties (4 hours)
In this experiment, the students are required to master the relation between dissociation equilibrium and other equilibrium. Comparing stability of the coordination compounds from equipment of coordination ions and how to appraisal these compounds are also needed to be mastered.
Experiment ten: separation on mix ions and the analysis (4 hours)
In this experiment, the students are required to master the properties of some ions and their compounds, to master how to analysis and separate these ions from their solutions, and deep understand applications of ions equilibrium.
Experiment eleven: properties and analysis of acids in toilet bowl cleaner (4 hours)
From the experiment, students are required to master the composition of toilet bowl cleaner and to analysis the contents of these acids.
Experiment twelve: Synthesis and the composition determination of potassium bioxalatocopper (II) (7 hours)
Students should understand the principles and method of the preparation for potassium bioxalatocopper (III). The principles and methods of EDTA for the detection of Cu2+ should be paid attention. The whole experiment involves dissolution, precipitation, washing, evaporation, concentration, crystallization, titration and other basic operations.
Ⅳ. Assignments
Students are required to finish the experimental report.
Ⅴ. Grading and Assessment
Ordinary mark is 70%, preview is 20%, operation is 40%, and the experiment report is 40%.
End semester test is 30%.
Ⅵ. Author
Zhang Lidan Jin Lan Cao Ding Zhang Chunting
2016.10.26